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### Course: MCAT > Unit 10

Lesson 18: Kinetics- Kinetics questions
- Introduction to reaction rates
- Rate law and reaction order
- Worked example: Determining a rate law using initial rates data
- First-order reaction (with calculus)
- Plotting data for a first-order reaction
- Half-life of a first-order reaction
- Worked example: Using the first-order integrated rate law and half-life equations
- Second-order reaction (with calculus)
- Half-life of a second-order reaction
- Zero-order reaction (with calculus)
- Collision theory
- The Arrhenius equation
- Forms of the Arrhenius equation
- Using the Arrhenius equation
- Elementary reactions
- Reaction mechanism and rate law
- Catalysts
- Kinetic and thermodynamic enolates

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# Rate law and reaction order

A rate law shows how the rate of a chemical reaction depends on reactant concentration. For a reaction such as

*a*A → products, the rate law generally has the form rate =*k*[A]*ⁿ*, where*k*is a proportionality constant called the rate constant and*n*is the order of the reaction with respect to A. The value of*n*is not related to the reaction stoichiometry and must be determined by experiment. Created by Jay.## Want to join the conversation?

- How to know the value of rate constant for any reaction? Is it different for different reactions?(14 votes)
- The rate constant for a chemical reaction is usually determined by experiment.(36 votes)

- These examples have such unrealistic amounts (1.00, 0.10, 2.00, 0.20). I just don't see the process at which you figured out what factor the rates were increased besides just knowing that 1 increased to 2, duh! What if I had numbers like [A]= 0.40, 0.60, 0.80 & [B]= 0.30, 0.30, 0.60? how does one figure out what factor each reactant has increased by?(5 votes)
- well the "process" here is simply division. 2 divided by 1 is 2. or it could've just as easily been 0.742321 becoming 1.484642. It's just to illustrate the point. With more complicated numbers, just use a calculator.(1 vote)

- So the constant K is from what thing? Is it from temperature, pressure etc.....(6 votes)
- It is constant for a specific temperature and a specific reaction.(16 votes)

- What is an order of reaction? What does it mean to be the first order and second order? And does the order correspond to x and y?

Thank you(2 votes)- The order of reaction determines the relationship between the rate of reaction and the concentration of reactants or products. It is the power to which a concentration is raised in the rate law equation.

For example, for the reaction xA + yB ---> products, the rate law equation will be as follows:

Rate = k[A]^a . [B]^b. This reaction is a order with respect to A and b order with respect to B. Overall, it is a + b order.

The order of reaction is something that has to be determined experimentally and can't usually be obtained from the stoichiometric coefficients (x and y).

Reactions are usually zero, first, second or third order, but can be anything, including fractional orders or even negative orders. The order affects what the graphs of concentration against time look like, how half-lives are calculated, etc.(14 votes)

- Does the rate constant, k have a specific value? Or is it different each time, or is it just a variable?(2 votes)
- The rate constant, k, has to be determined for each experiment (or set of data). The orders of each rate of reactants and products (for a particular experiment) help determine the units for k within that experiment. The next video develops this idea more fully.(10 votes)

- what is the reasons for a reaction to be of zero order?(2 votes)
- A zero order reaction is independent of the concentration of the reactants. One example could be an enzyme-catalysed reaction, where the enzyme is not (by definition) a reactant, but nevertheless the concentration of enzyme is what determines the reaction rate, not the concentration of reactant. This would be a zero order reaction.(5 votes)

- I got the math part. But I'm still really in the dark about how this applies to chemistry in the lab and what the answer helps me determine.(4 votes)
- How to I determine reaction order when only given the rate law??(3 votes)
- The exponent corresponding to each reactant will tell you what the reaction order is with respect to the pertaining reactant.

The overall reaction order is the sum of the individual orders of the reactants (which as said before are represented by the exponents in the rate law.(1 vote)

- 5:48- what are the units of the rate constant in? I understand that the units for [A] and [B] are in molarity (right?), but what about the rate constant?

How do we know what the rate constant is for a reaction? Do these rate constants vary by each different kind of reaction?(2 votes)- See the next video in this playlist, it depends on the order of the reaction(3 votes)

- What is the importance of coefficient in this case? For example, in the first example, if we have 2A + B -> Products, will the coefficient affect the final answer?(2 votes)
- The coefficients will simply tell you the ratio of reactants and products. It will (almost always) not change the outcome(3 votes)

## Video transcript

- [Voiceover] Let's take
a reaction where A plus B gives us our products. And the lower case a and the lower case b represent the coefficients
for our balanced equation. It makes sense if we increase
the concentration of A and B, right, A and B would be
closer together in space and more likely to react, therefore increasing the
rate of our reaction. And this is true for most reactions. If you increase the
concentration of your reactants, you increase the rate of your reaction. We can check this by
doing some experiments. So let's say we wanna figure out what the effect of the
concentration of A has on our rate of our reaction. So we're gonna hold the
concentration of B constant, so we hold the concentration of B constant in our experiments. We change the concentration of A, and we see what effect that has
on the rate of our reaction. We're going to use the
initial rate of the reaction. And that's because as
our reaction proceeds, the concentration of
products will increase. And since reactions are reversible, if we have some products present, right, that can affect the rate of our reaction. And that's not our goal. Our goal is to figure out
what the concentration, what effect the concentration
of our reactants has on our rate. And so we use the initial rate, where we have only reactants present, and no products. So in our first experiment, let's say the concentration
of A is one molar, and the rate of our reaction, the initial rate of our reaction is .01 molar per second. And our second experiment, we increase the concentration
of A to two molar. We hold the concentration of B constant, and we observe the rate of our reaction to increase to .02 molar per second. So we've increased the concentration of A by a factor of two. And what happened to our rate? Our rate went from .01 to .02. So the rate increased by two as well. All right, let's compare
our first experiment with our third experiment now. We're going from a
concentration of A of one, to a concentration of A of three. So we've increased the concentration of A by a factor of three. And what happened to the rate? The rate went from .01 to .03. So the rate increased
by a factor of three. All right, to figure out the relationship, if you think to yourself,
two to what power X is equal to two? Obviously that would be two to the first. Two to the first is equal to two. All right, we could have done it for our other comparison as well. Three to what power X is equal to three? Obviously three to the
first is equal to three. So the rate, the rate of our
reaction is proportional to, and that's what this
funny symbol means here, the rate of our reaction is proportional to the concentration of
A to the first power. All right, let's do the same thing for the concentration of B. So we do some experiments where we change the concentration of B, and we see what effect that
has on our initial rate. So for all of these, we're gonna hold the
concentration of A constant, therefore, whatever we
do to B is reflected in the rate of our reaction. So in our first experiment, the concentration of B is one molar and the rate is .01 molar per second. And then we change the
concentration of B to two molar. Right, we double the concentration of B while holding the
concentration of A constant. And we observe the initial
rate of our reaction to be .04 molar per second. So we've increased the
concentration of B, not A, and let me change that (laughs). We've increased the concentration of B by a factor of two. We've gone from one molar to two molar. And what happened to the rate? The rate went from .01 to .04. So we've increased the
rate by a factor of four. Let's compare our first experiment with our third experiment now. We're going from a concentration of B of one molar to three molar. So we've increased the concentration of B by a factor of three. And what happens to the rate? The rate goes from .01 to .09. So we've increased the
rate by a factor of nine. So now we think to
ourself, two to what power, I'll make it Y, two to what power is equal to four? Obviously Y would be equal to two. Two to the second power is equal to four. Or three to what power Y is equal to nine? Obviously, three to the
second power is equal to nine. So we've determined that
the rate of our reaction is proportional to the concentration of B to the second power. All right, now we can put those together. We can put these together to write what's called a rate law. Ok, So we know that the
rate of our reaction is proportional to the concentration of A to the first power, and we know that our rate is proportional to the concentration of
B to the second power. And then we put in, we
put in what's called a rate constant here, K. And this represents our rate law. So let's go through these one by one here. So, capital R is the rate
of our reaction, right? This is the rate of our reaction. All right? K is what's called the rate constant. So this is the rate constant. And there's a difference
between the rate of our reaction and the rate constant. If we change the concentration
of our reactants, we change the rate of our reaction. But if we change the
concentration of our reactants, we don't change the rate constants, right? And this is constant. It does depend on the temperature, though, so we'll talk about that in later videos. Here we have that the reaction is concentration of A to the first power. We say the reaction is first order in A. So we say that our
reaction is first order, first order in A. And we found, we found that
it's second order in B. Right, so we had a two here. So this is second order, second order in B. And we can also talk
about the overall order of our reaction. So if we're first order in A, right, we're first order in A, and second order in B, the overall order, the overall order would be one plus two,
which is equal to three. So the overall order of
our reaction is three. All right, let's go back up
here to the general reaction that we started with, all right, so let's go back, right back up to here. We have, we have this. And let's write a general rate law. So if this is your reaction,
your general rate law would be R is equal to your rate constant, times the concentration
of A to some power, I'll make it X, times
the concentration of B to some power which I will make Y. And the reason why I'm showing you this, is to show you that you can't
just take your coefficients, right, you can't take your coefficients and stick them into here. Right? So it doesn't work that way. You'd have to know the
mechanism of your reaction. So these orders have to be
determined experimentally. So you have to look at your
experimental data here. And the orders affect the
units for your rate constant. For example, let's go back down to here. And let's figure out the
units for the rate constant for this example. So the rate of our reaction, the rate of our reaction was
in molar per seconds, right? This is molar per second. We're trying to find the units for K. The units for concentration are molar. All right, so this would be molar, and this would be to the first power. And this would be molar
to the second power. So we'd have molar to the second power. All right, so solving for K, right, you could just go ahead and cancel out one of these molars right
here, and solve for K. So you would get, this
would be one over seconds now on the left. So one over seconds, right,
and divide by molar squared. So one over seconds times molar squared. Or you could write this one over molar squared times seconds. Those would be your units for K for this reaction, right? With an overall order of three. But it can change. Right? It can change depending on the order. Now let's look at this reaction. We have only one reactant, A, turning into our products. And if we look at the two experiments, in our first experiment,
the concentration of A is one molar, and the
initial rate of reaction is .01 molar per second. If we double the concentration
of A to two molar, the rate stays the same. It's still point zero
one molar per second. So even though the concentration of A is going from one molar to two molar, right, that's doubling the concentration, or increasing the concentration
of A by a factor of two, the rate stays the same. So you could say, the rate,
it's the rate times one. 'Cause it's the same rate. So two, all right, so two to what power X, two to what power X is equal to one? Obviously X would have
to be equal to zero. Two to the zero power is equal to one. So any number to the zero
power is equal to one. So this reaction is zero order, it's zero order in A. Now if we wanted to write our rate law, we would write the rate of the reaction is equal to the rate constant K times the concentration of A. We have only one reactant here. And since this is zero order in A, we could just write the
rate of the reaction is equal to the rate constant K. And so if you wanted to know the units for the rate constant K, well, the rate is in molar per second. And so those would also
be your units for K. K would be in molar per second. So here's an example of how
your units for K change, depending on the overall
order of your reaction.